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The Betrand group (University of California) have reported a doubly oxidized carbene species with just four valence electrons, CSD Entry NITRUH (https://ccdc-info.com/3LWNHCr). This dicationic structure is formed from the carbene in two steps via an intermediate singly oxidized molecule (CSD Entry NITSAO). The carbon centre of the doubly oxidized carbene species is stabilized by bulky electron-rich groups, it maintains strong electrophilicity forming an adduct with DMAP (CSD Entry NITSIW), and i
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